Applications of analytical electron microscopy to guide the design of boron carbide

Compositional analysis of boron carbide on nanometer length scales to examine or interpret atomic mechanisms, for example, solid-state amorphization or grain-boundary segregation, is challenging. This work reviews advancements in high-resolution microanalysis to characterize multiple generations of boron carbide. First, ζ-factor microanalysis will be introduced as a powerful (scanning) transmission electron microscopy ((S)TEM) analytical framework to accurately characterize boron carbide. Three case studies involving the application of ζ-factor microanalysis will then be presented: (1) accurate stoichiometry determination of B-doped boron carbide using ζ-factor microanalysis and electron energy loss spectroscopy, (2) normalized quantification of silicon grain-boundary segregation in Si-doped boron carbide, and (3) calibration of a scanning electron microscope X-ray energy-dispersive spectroscopy (XEDS) system to measure compositional homogeneity differences of B/Si-doped arc-melted boron carbides in the as-melted and annealed conditions. Overall, the improvement and application of advanced analytical tools have helped better understand processing–microstructure–property relationships and successfully manufacture high-performance ceramics.     

Life cycle assessment of HFC-134a production by calcium carbide acetylene route in China

HFC-134a is a widely used environment-friendly refrigerant. At present, China is the largest producer of HFC-134a in the world. The production of HFC-134a in China mainly adopts the calcium carbide acetylene route. However, the production route has high resource and energy consumption and large waste emission, and few of the studies addressed on the environmental performance of its production process. This study quantified the environmental performance of HFC-134a production by calcium carbide route via carrying out a life cycle assessment (LCA) using the CML 2001 method. And uncertainty analysis by Monte-Carlo simulation was also carried out. The results showed that electricity had the most impact on the environment, followed by steam, hydrogen fluoride and chlorine, and the impact of direct CO₂ emissions in calcium carbide production stage on the global warming effect also could not be ignored. Therefore, the clean energy (e.g., wind, solar, biomass, and natural gas) was used to replace coal-based electricity and coal-fired steam in this study, showing considerable environmental benefits. At the same time, the use of advanced production technologies could also improve environmental benefits, and the environmental impact of the global warming category could be reduced by 4.1% via using CO₂ capture and purification technology. The Chinese database of HFC-134a production established in this study provides convenience for the relevant study of scholars. For the production of HFC-134a, this study helps to better identify the specific environmental hotspots and proposes useful ways to improve the environmental benefits.     

Fine-diameter Si–B–C–N ceramic fibers enabled by polyborosilazanes with N–methyl pendant group

Given the superior thermal stability and electromagnetic features, continuous Si–B–(C)–N ceramic fibers have displayed great potential to fulfill the increasing demand for the high-temperature structural and functional materials. Manufacture of such ceramic fibers depends heavily upon the design of processable polymer precursors. Herein, a class of polyborosilazanes (PBSZs) with high spinnability were created through a facile one-pot synthesis. The trade-off between spinnability and ceramic yield of PBSZs was overcome by using heptamethyldisilazane and hexamethyldisilazane as the co-condensing agents to polymerize silicon and boron chloride monomers. The optimal PBSZs can fabricate continuous Si–B–C–N fibers with homogeneous diameter of 7.9 ± 0.5 μm and high ceramic yield of 80 wt%. Experimental characterization and quantum chemical computation revealed the mechanistic pictures of the impact of pendant groups on the polycondensation, melt spinning, and pyrolyzing process. These insights improve our understanding of spinnable pre-ceramic polymers for exploiting high-performance nitride ceramic fibers.     

镍基高温合金GH202高温氧化后的微观组织演变

研究了镍基高温合金GH202在800~1100 ℃高温氧化后晶粒、碳化物和强化相的演变过程。采用透射电子显微镜、扫描电子显微镜和电子背散射衍射对其微观结构进行了表征。结果表明：镍基高温合金的硬度随氧化温度的升高而降低，1100 ℃氧化100 h后，硬度降低了43.5%。800和900 ℃氧化后晶粒生长速度较慢，而经900 ℃氧化后晶界碳化物析出显著增加。在1000和1100 ℃氧化后，晶粒尺寸明显增大。氧化过程中晶界迁移是由晶界两侧自由能差决定，温度越高，晶界向曲率中心迁移越快，大量细小晶粒被吞并形成了大晶粒。大块状碳化物（MC）分解成大量的碳原子，与Cr原子结合形成少量的富Cr颗粒状M₂₃C₆。在900 ℃氧化150 h后，M₂₃C₆演化为富Ti的M₆C。随着氧化温度的升高，碳化物在γ相中回熔。在800、900和1000 ℃氧化后，γ′相逐渐长大，在1100 ℃氧化100 h后，完全溶解于γ相。     

Piezoelectric properties of PVDF-conjugated polymer nanofibers

This study presents the development and characterization of PVDF-conjugated polymer nanofiber-based systems. Five different conducting polymers (CPs) were synthesized successfully and used to create the nanofiber systems. The CPs used are polyaniline (PANI), polypyrrole (PPY), polyindole (PIN), polyanthranilic acid (PANA), and polycarbazole (PCZ). Nanofiber systems were produced utilizing the Forcespinning® technique. The nanofiber systems were developed by mechanical stretching. No electrical field or post-process poling was used in the nanofiber systems. The morphology, structure, electrochemical and piezoelectric performance was characterized. All of the nanofiber PVDF/CP systems displayed higher piezoelectric performance than the fine fiber PVDF systems. The PVDF/PPY nanofiber system displays the highest piezoelectric performance of 15.56 V. The piezoelectric performance of the PVDF/CP nanofiber systems favors potential for an attractive source of energy where highly flexible membranes could be used in power actuators, sensors and portable, and wireless devices to mention some.     

Enhanced dielectric and piezoelectric properties in potassium sodium niobate/polyvinylidene fluoride composites using nano-silicon carbide as an additive

Piezoelectric materials are an indispensable part of modern life. Yet the existing environmental issues with conventional lead-based piezoelectrics has motivated scientist to develop novel substitutes including lead-free piezoelectric polymer composites. Following this path, the present research has focused on the fabrication of ternary composites of Polyvinylidene fluoride (PVDF)/Potassium Sodium Niobate (KNN)/nano-Silicon carbide (SiC) via hot compression molding and studying the effect of additives on the PVDF structure and the electrical properties of the composite. The obtained scanning electron micrographs and density measurements showed that the fabrication method provided dense samples. The activated polarization phenomena in the prepared samples enhanced dielectric permittivity and dielectric loss at a constant frequency with increasing KNN and SiC contents. Besides the expected dipole polarization, the presence of interfaces in the composites gave rise to the Maxwell–Wagner–Sillars effect and its corresponding polarization phenomenon. The semiconductive nature of SiC also promoted space charge polarization. However, these properties were frequency-dependent because the first two polarization mechanisms are deactivated at high frequencies. XRD patterns showed that SiC addition can alter the primary crystalline structure of PVDF and promote β-phase formation in the poled samples. Piezoelectric measurements confirmed the significant role of SiC addition to PVDF-KNN composites. The most significant increase in the piezoelectric properties was observed in PVDF-60KNN-1SiC, with a 183% increase in d₃₃ value. The PVDF-80KNN-1SiC had the highest d₃₃ value of 30.5 pC/N. It also had the best piezoelectric voltage coefficient and hence the highest figure of merit. Higher SiC contents restrict the efficiency of poling by forming a conductive path across the sample which would deteriorate the piezoelectric performance of the material. The present findings show that PVDF-KNN-SiC composites can be considered as a potential flexible piezoelectric material for future applications.     

多晶硅表面金属催化化学腐蚀法制绒研究现状

在多晶硅太阳能电池的生产过程中, 金刚线切割技术(Diamond wire sawn, DWS)具有切割速度快、精度高、原材料损耗少等优点, 受到了广泛关注。金刚线切割多晶硅表面形成的损伤层较浅, 与传统的酸腐蚀制绒技术无法匹配, 金属催化化学腐蚀法应运而生。金属催化化学腐蚀法制绒具有操作简单、结构可控且易形成高深宽比的绒面等优点, 具有广阔的应用前景。本文总结了不同类型的金属催化剂在制绒过程中的腐蚀机理及其形成的绒面结构, 深入分析和讨论了具有代表性的银、铜的单一及复合催化腐蚀过程及绒面结构和电池片性能。最后对金刚线切割多晶硅片表面的金属催化化学腐蚀法存在的问题进行了分析, 并展望了未来的研究方向。     

Investigation the effect of FeNiCoCrMo HEA addition on properties of B4C ceramic prepared by spark plasma sintering

In this study, monolithic B₄C and B₄C-based ceramics incorporating FeNiCoCrMo dual-phase (FCC and BCC) high entropy alloys (HEAs) were produced by spark plasma sintering (SPS). The effect of additives on the densification behavior, mechanical properties, microstructures, and phase evaluation of the samples were investigated. X-ray analysis confirmed the existence of FCC structured HEA and depletion of BCC structured HEA, after high-temperature reaction between B₄C-HEAs. The addition of HEAs enhanced the densification behavior by liquid phase sintering. Furthermore, hardness and fracture toughness values of the samples increased with increasing HEAs content. Fracture toughness and hardness values for all composites were higher than the monolithic B₄C. A combination of the highest density (∼99.22 %) and the best mechanical properties (32.3 GPa hardness and 4.53 MPa m^1/2 fracture toughness) was achieved with 2.00 vol.% HEA addition.     

Investigation on thermal conductivity and mechanical properties of Si3N4 ceramics via one-step sintering

High thermal conductivity Si₃N₄ ceramics were fabricated using a one-step method consisting of reaction-bonded Si₃N₄ (RBSN) and post-sintering. The influence of Si content on nitridation rate, β/(α+β) phase rate, thermal conductivity and mechanical properties was investigated in this work. It is of special interest to note that the thermal conductivity showed a tendency to increase first and then decrease with increasing Si content. This experimental result shows that the optimal thermal conductivity and fracture toughness were obtained to be 66 W (m K)^-1 and 12.0 MPa m^1/2, respectively. As a comparison, the nitridation rate and β/(α+β) phase rate in a static pressure nitriding system, i.e., 97% (MS10), 97% (MS15), 97% (MS20) and 8.3% (MS10), 8.3% (MS15), 8.9% (MS20), respectively, have obvious advantages over those in a flowing nitriding system, i.e., 91% (MS10), 91% (MS15), 93% (MS20) and 3.1% (MS10), 3.3% (MS15), 3.3% (MS20), respectively. Moreover, high lattice integrity of the β-Si₃N₄ phase was observed, which can effectively confine O atoms into the β-Si₃N₄ lattice using MgO as a sintering additive. This result indicates that one-step sintering can provide a new route to prepare Si₃N₄ ceramics with a good combination of thermal conductivity and mechanical properties.